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crevice corrosion


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Catégorie :Category: nCreator TI-Nspire
Auteur Author: oONOLTZOo
Type : Classeur 3.0.1
Page(s) : 1
Taille Size: 3.01 Ko KB
Mis en ligne Uploaded: 23/10/2024 - 12:08:19
Uploadeur Uploader: oONOLTZOo (Profil)
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Visibilité Visibility: Archive publique
Shortlink : http://ti-pla.net/a4270501

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Fichier Nspire généré sur TI-Planet.org.

Compatible OS 3.0 et ultérieurs.

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You are provided with an image, shown in Figure 3, of astainless steel part that has been exposed to a corrosive environment. The partexhibits signs of crevice corrosion. Figure 3: Crevice corrosion a)      Identifythe signs of crevice corrosion evident in the image. a) Signs of Crevice Corrosion Crevice corrosion is often characterizedby specific visual cues, which may include: Localized Pitting : Small, deep pits or holes in the surface of the metal, indicating where corrosion has concentrated. Surface Discoloration : Changes in color, often a dull, rough appearance or darkened areas where corrosion has occurred. Material Loss : Areas where the material appears to be missing or has corroded away significantly more than surrounding areas. Crevice Formation : Visible gaps or spaces, especially where two surfaces meet (like flanges, gaskets, or welds), indicating that corrosive agents have accumulated.   b) Explain the reason and mechanism of how this corrosionoccurs in metallic materials. Write the anodic and cathodic reactions involvedin the corrosion process. Clearly label each reaction and indicate where theyoccur on the metal surface. Reason and Mechanism : Crevice corrosion occurs in confinedspaces where the electrolyte (usually water with corrosive ions) becomesstagnant. The primary factors contributing to this type of corrosion include: Oxygen Depletion : Inside the crevice, oxygen levels can drop significantly compared to the exposed surface, creating a differential aeration cell. Ion Concentration : Accumulation of aggressive ions (like chloride) in the crevice can increase corrosion rates. pH Changes : The pH level may decrease due to localized electrochemical reactions, making the environment more acidic and aggressive towards the metal. Anodic Reaction (Metal Oxidation): This occurs at the site of corrosion (inside the crevice): Fe’Fe2++25R (Iron is oxidized, resulting in iron ions and releasingelectrons) Cathodic Reaction (Reduction of Oxygen): This occurs at the exposed metal surface: O2+2H2O+45R’4OH (Oxygen reduction occurs, leading to hydroxide ion formation)   c)      Discussstrategies to prevent crevice corrosion in stainless steel components used incorrosive environments. Material Selection : Use higher-grade stainless steels (e.g., 316L) with better resistance to crevice corrosion, particularly in chloride environments. Design Considerations : Avoid designs that create tight crevices where water can accumulate. Use smooth, continuous surfaces and minimize the use of gaskets or flanges where possible. Protective Coatings : Apply protective coatings (such as paint or specialized corrosion-resistant coatings) to the surfaces to create a barrier against corrosive agents. Cathodic Protection : Implement cathodic protection systems that provide an external source of electrons to reduce the anodic reaction and protect the metal from corrosion. Regular Maintenance : Conduct regular inspections and maintenance to identify and mitigate early signs of crevice corrosion before they become significant problems. Water Management : Implement drainage systems to prevent water accumulation in crevices and promote the flow of electrolyte away from vulnerable areas.   Made with nCreator - tiplanet.org
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